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The invention relates to a refinement method of a rubber vulcanization accelerator MBT (2-mercaptobenzthiazole), which comprises the following steps: adding crude MBT into a reactor filled with a 2-30 wt% NaOH solution, and keeping the temperature in the reactor at 60-90 DEG C until the MBT is dissolved into an M-Na salt solution and the end point pH value of the solution is kept at 9.5-12.5 ...
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